反铁电性
材料科学
电介质
陶瓷
铁电性
电场
电容器
储能
极化(电化学)
光电子学
凝聚态物理
电压
复合材料
电气工程
热力学
功率(物理)
物理
量子力学
工程类
化学
物理化学
作者
Tianze Pan,Ji Zhang,Dongxiao Che,Zhenyu Wang,Jiajia Wang,Jing Wang,Yaojin Wang
摘要
Ceramic-based dielectric capacitors have become an attractive issue due to their wide applications in current pulsed-/high-power electronic devices. Antiferroelectric ceramics generally exhibit ultrahigh energy density owing to their giant polarization activated by antiferroelectric–ferroelectric phase transition under a high electric field but suffer from large hysteresis, meanwhile giving rise to low efficiency. Herein, by introducing perovskite compound Sr(Fe0.5Ta0.5)O3 into an antiferroelectric NaNbO3 matrix, a stabilized antiferroelectric phase and an improved relaxor behavior are observed. That is, relaxor antiferroelectric ceramics are constructed. Accordingly, a double polarization–electric field (P–E) loop becomes slimmer with increasing incorporation of dopants, leading to an ultrahigh recoverable energy density of 11.5 J/cm3, an energy storage efficiency of 86.2%, outstanding frequency/cycling/thermal reliability, and charge–discharge properties in 0.90NaNbO3-0.10Sr(Fe0.5Ta0.5)O3 ceramics. This work reveals that inducing the relaxor behavior in antiferroelectric materials is an effective route to improve their capacitive energy storage.
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