化学
芳基
组合化学
可见光谱
光化学
立体化学
有机化学
光电子学
物理
烷基
作者
Luca Nicchio,Lorenzo Di Terlizzi,Luc Neuville,Maurizio Fagnoni,Stefano Protti,Géraldine Masson
标识
DOI:10.1002/adsc.202401251
摘要
We present a novel and highly efficient method for synthesizing polyfunctionalized 1,2,4‐triazoles. This approach leverages visible light and arylazo sulfones in combination with N‐vinyl amides, in the environmentally friendly solvent ethyl acetate. Remarkably, the reaction proceeds without the need for (photo)catalysts, ensuring near‐perfect atom economy and producing only water as a by‐product. This method exhibits excellent functional group tolerance and can be scaled for both batch and continuous‐flow processes.
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