Spatial separation of redox centers for boosting cooperative photocatalytic hydrogen evolution with oxidation coupling of benzylamine over Pt@UiO-66-NH2@ZnIn2S4

Pt@UiO-66-NH 2 @ZIS is prepared to realize the co-production of H 2 and C–N coupling products. DFT calculations of interfacial charges reveal that spatial separation of redox centers has a significant catalytic effect on dual-functional systems.