催化作用
原材料
环氧化物
材料科学
环加成
化学
有机化学
作者
Carla Calabrese,Francesco Giacalone,Carmela Aprile
出处
期刊:Catalysts
[Multidisciplinary Digital Publishing Institute]
日期:2019-04-02
卷期号:9 (4): 325-325
被引量:85
摘要
The conversion of carbon dioxide into valuable chemicals such as cyclic carbonates is an appealing topic for the scientific community due to the possibility of valorizing waste into an inexpensive, available, nontoxic, and renewable carbon feedstock. In this regard, last-generation heterogeneous catalysts are of great interest owing to their high catalytic activity, robustness, and easy recovery and recycling. In the present review, recent advances on CO2 cycloaddition to epoxide mediated by hybrid catalysts through organometallic or organo-catalytic species supported onto silica-, nanocarbon-, and metal–organic framework (MOF)-based heterogeneous materials, are highlighted and discussed.
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