材料科学
格式化
铋
电催化剂
介孔材料
法拉第效率
选择性
锡
析氧
太阳能燃料
纳米技术
无机化学
化学工程
催化作用
阳极
电极
电化学
光催化
冶金
化学
物理化学
有机化学
工程类
作者
Hui Yang,Na Han,Jun Deng,Jinghua Wu,Yu Wang,Yongpan Hu,Ding Pan,Yafei Li,Yanguang Li,Jun Lü
标识
DOI:10.1002/aenm.201801536
摘要
Abstract The conversion of CO 2 to value‐added products using electrical or solar energy represents an attractive means for the capture and utilization of atmospheric CO 2 . Formate is a popular product from CO 2 reduction, but its reaction selectivity is usually unsatisfactory. Tin‐based materials have attracted the most attention for formate production at present. Unfortunately, most of them only exhibit moderate selectivity in a narrow and highly cathodic potential window. In this study, it is demonstrated that traditionally under‐explored bismuth has a much greater potential for formate production than tin or other materials. Mesoporous bismuth nanosheets are prepared here by the cathodic transformation of atomic‐thick bismuth oxycarbonate nanosheets. They enable the selective CO 2 reduction to formate with large current density, excellent Faradaic efficiency (≈100%) over a broad potential window and great operation stability. Moreover, Bi nanosheets are integrated with an oxygen evolution reaction electrocatalyst in full cells, and achieve efficient and robust solar conversion of CO 2 /H 2 O to formate/O 2 .
科研通智能强力驱动
Strongly Powered by AbleSci AI