Spatial positioning effect of dual cocatalysts accelerating charge transfer in three dimensionally ordered macroporous g-C3N4 for photocatalytic hydrogen evolution

• A promising dual cocatalysts intensified 3DOM g-C 3 N 4 photocatalyst was developed. • The spatial positioning effect of dual cocatalysts was investigated. • The average wall thickness of 3DOM g-C 3 N 4 framework can be precisely controlled. • The ordered charges transfer was significantly enhanced. • The CoP/3DOM g-C 3 N 4 /Au show high activity of photocatalytic hydrogen evolution . The relatively low charge transfer efficiency remains the critical limiting factor for the practical application of solar-driven water splitting. In this work, a promising photocatalyst intensified by dual cocatalysts was developed via separately loading Au nanoparticles and CoP nanosheets onto the inside and outside surface of three dimensionally ordered macroporous (3DOM) g-C 3 N 4 framework to significantly facilitate the ordered transfer of charges. The spatial positioning of dual cocatalysts and average wall thickness of 3DOM g-C 3 N 4 framework were precisely controlled to reveal the optimal distribution position of Au and CoP as well as the most appropriate transfer distance for charges (from 3DOM g-C 3 N 4 walls to the surface of cocatalysts), respectively. The results show that the spatial positioning effect of dual cocatalysts and optimization of charge transfer distance can endow the CoP/3DOM g-C 3 N 4 /Au photocatalyst with an excellent charge transfer efficiency, thereby contributing to high apparent quantum efficiency (AQE, 27.6% at 435 nm and 29.9% at 550 nm) and photocatalytic H 2 evolution activity of 11,820.1 μmol h −1 g −1 , which is up to 619.9, 6.5 and 5.6 times than that of 3DOM g-C 3 N 4 , CoP/3DOM g-C 3 N 4 and 3DOM g-C 3 N 4 /Au, respectively. This work would provide a new platform to design high-performance artificial photocatalysts with superior charge transfer capacity.