Defect Engineering in Manganese‐Based Oxides for Aqueous Rechargeable Zinc‐Ion Batteries: A Review

Advanced Energy MaterialsVolume 10, Issue 34 2001769 Review Defect Engineering in Manganese-Based Oxides for Aqueous Rechargeable Zinc-Ion Batteries: A Review Ting Xiong, Ting Xiong Department of Materials Science and Engineering, National University of Singapore, Singapore, 117573 Singapore Centre for Advanced 2D Materials and Graphene Research Centre, National University of Singapore, Singapore, 117546 SingaporeSearch for more papers by this authorYaoxin Zhang, Yaoxin Zhang Department of Materials Science and Engineering, National University of Singapore, Singapore, 117573 SingaporeSearch for more papers by this authorWee Siang Vincent Lee, Corresponding Author Wee Siang Vincent Lee mseleew@nus.edu.sg Department of Materials Science and Engineering, National University of Singapore, Singapore, 117573 Singapore E-mail: mseleew@nus.edu.sg, msexuejm@nus.edu.sgSearch for more papers by this authorJunmin Xue, Corresponding Author Junmin Xue msexuejm@nus.edu.sg orcid.org/0000-0003-3349-1873 Department of Materials Science and Engineering, National University of Singapore, Singapore, 117573 Singapore E-mail: mseleew@nus.edu.sg, msexuejm@nus.edu.sgSearch for more papers by this author Ting Xiong, Ting Xiong Department of Materials Science and Engineering, National University of Singapore, Singapore, 117573 Singapore Centre for Advanced 2D Materials and Graphene Research Centre, National University of Singapore, Singapore, 117546 SingaporeSearch for more papers by this authorYaoxin Zhang, Yaoxin Zhang Department of Materials Science and Engineering, National University of Singapore, Singapore, 117573 SingaporeSearch for more papers by this authorWee Siang Vincent Lee, Corresponding Author Wee Siang Vincent Lee mseleew@nus.edu.sg Department of Materials Science and Engineering, National University of Singapore, Singapore, 117573 Singapore E-mail: mseleew@nus.edu.sg, msexuejm@nus.edu.sgSearch for more papers by this authorJunmin Xue, Corresponding Author Junmin Xue msexuejm@nus.edu.sg orcid.org/0000-0003-3349-1873 Department of Materials Science and Engineering, National University of Singapore, Singapore, 117573 Singapore E-mail: mseleew@nus.edu.sg, msexuejm@nus.edu.sgSearch for more papers by this author First published: 29 July 2020 https://doi.org/10.1002/aenm.202001769Citations: 152Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Abstract The development of advanced cathode materials for aqueous the zinc ion battery (ZIB) represents a crucial step toward building future large-scale green energy conversion and storage systems. Recently, significant progress has been achieved in the development of manganese-based oxides for ZIB via defect engineering, whereby the intrinsic capacity and energy density have been enhanced. In this review, an overview of the recent progress in the defect engineering of manganese-based oxides for aqueous ZIBs is summarized in the following order: 1) the structures and properties of the commonly used manganese-based oxides, 2) the classification of the various types of defect engineering commonly reported, 3) the various strategies used to create defects in materials, and 4) the effects of the various types of defect engineering on the electrochemical performance of manganese-based oxides. Finally, a perspective on the defect engineering of manganese-based oxides is proposed to further enhance their electrochemical performance as a ZIB cathode. Conflict of Interest The authors declare no conflict of interest. Citing Literature Volume10, Issue34September 8, 20202001769 RelatedInformation