Simultaneous Power Conversion Efficiency and Stability Enhancement of Cs 2 AgBiBr 6 Lead‐Free Inorganic Perovskite Solar Cell through Adopting a Multifunctional Dye Interlayer

Abstract Perovskite solar cells (PSCs) are highly promising next‐generation photovoltaic devices because of the cheap raw materials, ideal band gap of ≈1.5 eV, broad absorption range, and high absorption coefficient. Although lead‐based inorganic‐organic PSC has achieved the highest power conversion efficiency (PCE) of 25.2%, the toxic nature of lead and poor stability strongly limits the commercialization. Lead‐free inorganic PSCs are potential alternatives to toxic and unstable organic‐inorganic PSCs. Particularly, double‐perovskite Cs 2 AgBiBr 6 ‐based PSC has received interests for its all inorganic and lead‐free features. However, the PCE is limited by the inherent and extrinsic defects of Cs 2 AgBiBr 6 films. Herein, an effective and facile strategy is reported for improving the PCE and stability by introducing an N719 dye interlayer, which plays multifunctional roles such as broadening the absorption spectrum, suppressing the charge carrier recombination, accelerating the hole extraction, and constructing an appropriate energy level alignment. Consequently, the optimizing cell delivers an outstanding PCE of 2.84%, much improved as compared with other Cs 2 AgBiBr 6 ‐based PSCs reported so far in the literature. Moreover, the N719 interlayer greatly enhances the stability of PSCs under ambient conditions. This work highlights a useful strategy to boost the PCE and stability of lead‐free Cs 2 AgBiBr 6 ‐based PSCs simultaneously, accelerating the commercialization of PSC technology.