Formation of Ni-doped MoS2 nanosheets on N-doped carbon nanotubes towards superior hydrogen evolution

塔菲尔方程 兴奋剂 碳纳米管 二硫化钼 电催化剂 煅烧 材料科学 催化作用 电导率 化学工程 无机化学 纳米技术 化学 电化学 复合材料 电极 有机化学 物理化学 光电子学 工程类
作者
Tao Dong,Xiao Zhang,Peng Wang,Hsueh‐Shih Chen,Ping Yang
出处
期刊:Electrochimica Acta [Elsevier BV]
卷期号:338: 135885-135885 被引量:84
标识
DOI:10.1016/j.electacta.2020.135885
摘要

Molybdenum disulfide (MoS2) is one of the promising candidates for hydrogen evolution reaction (HER), it’s HER properties can be extremely enhanced by the construction of nanostructure and the regulation of electronic structure. In this paper, hierarchical composites with MoS2 and carbon nanotubes (CNTs) as the noble metal-free electrocatalysts for HER were fabricated through calcination and hydrothermal processes, in which the MoS2 nanosheets with Ni atoms incorporation were vertically grown on the outsides of nitrogen (N)-doped CNTs. The constructed hierarchical structures provide large specific surface area of about 150 m2 g−1 and high structure stability. Importantly, the MoS2 nanosheets with enlarged interlayer spacing possess ultrathin structure of about 4 nm in thickness. Owing to the incorporation of Ni atoms, abundant unsaturated S atoms are obtained in the basal plane, which leading to more active sites exposed during HER processes. Meanwhile, N-doped CNTs can act as the substrate for MoS2 nanosheets growing and simultaneously improve the conductivity of catalyst. Based on the synergy of hierarchical structure, increased active sites and enhanced conductivity, the as-prepared electrocatalysts exhibit superior HER activity with low overpotentials, small Tafel slopes and long-time durability in both acidic and alkaline electrolytes. The overpotentials of 158 and 179 mV were required to drive HER current density up to 10 mA cm−2 in 0.5 M H2SO4 and 1.0 M KOH, respectively. This work reports a highly efficient MoS2-based electrocatalyst for HER via fabricating hierarchical structure and doping Ni atoms.
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