材料科学
锰
纳米颗粒
铁氧体(磁铁)
碳纳米管
矫顽力
β铁氧体
化学工程
复合材料
纳米技术
冶金
微观结构
凝聚态物理
奥氏体
物理
工程类
作者
Saja Al-Khabouri,S. H. Al-Harthi,Toru Maekawa,M. E. Elzain,Ashraf T. Al‐Hinai,A. D. Al-Rawas,A. M. Gismelseed,A. A. Yousif,Myo Tay Zar Myint
标识
DOI:10.3762/bjnano.11.170
摘要
Free and partially encapsulated manganese ferrite (MnFe 2 O 4 ) nanoparticles are synthesized and characterized regarding structure, surface, and electronic and magnetic properties. The preparation method of partially encapsulated manganese ferrite enables the formation of a hybrid nanoparticle/tube system, which exhibits properties of manganese ferrite nanoparticles inside and attached to the external surface of the tubes. The effect of having manganese ferrite nanoparticles inside the tubes is observed as a shift in the X-ray diffraction peaks and as an increase in stress, hyperfine field, and coercivity when compared to free manganese ferrite nanoparticles. On the other hand, a strong charge transfer from the multiwall carbon nanotubes is attributed to the attachment of manganese ferrite nanoparticles outside the tubes, which is detected by a significant decrease in the σ band emission of the ultraviolet photoemission spectroscopy signal. This is followed by an increase in the density of states at the Fermi level of the attached manganese ferrite nanoparticles in comparison to free manganese ferrite nanoparticles, which leads to an enhancement of the metallic properties.
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