Combining acid-based deep eutectic solvents and microwave irradiation for improved chestnut shell waste valorization

作者
José González-Rivera,Angelica Mero,Elena Husanu,Andrea Mezzetta,Carlo Ferrari,Felicia D'Andrea,Emilia Bramanti,Christian Silvio Pomelli,Lorenzo Guazzelli
出处
期刊:Green Chemistry [The Royal Society of Chemistry]
标识
DOI:10.1039/d1gc03450b
摘要

A microwave (MW)/deep eutectic solvent (DES)-assisted (MWDA) extraction process for obtaining value-added compounds from chestnut shell waste (CSW) is presented. DESs were used as green solvents featuring both high biomass dissolution ability and good response to MW irradiation. A survey of different acid-based DESs led to the identification of Choline Chloride (ChCl)–oxalic acid as the system most sensitive to experimental design variations, especially when considering the total phenolic content (TPC) and the total mass amount recovered (yield wt%). Hence, the MW absorption properties of ChCl–oxalic acid dihydrate and ChCl–oxalic acid DESs, as single components and in mixture with water, were assessed by the experimental determination of their MW heating response. Moreover, the extraction efficiency for the best MW responding system, ChCl–oxalic acid dihydrate, was evaluated at different MW-irradiation times and extraction temperatures. The isolated polyphenols from CSW were further characterized by HPLC-DAD analysis. Gallic acid, ellagic acid, catechin hydrate and procyanidin B2 were identified and quantified, with their relative ratios varying as a function of the MWDA extraction conditions. Lignin, hemicellulose and cellulose compositions of the solid residues of CSW after the MWDA extraction were assessed using a cross validation model obtained by partial least squares regression (PLS) of their FTIR spectra. The chemometrics results, corroborated by SEM analyses, highlighted the ability of the oxalic acid-based DES to simultaneously remove lignin during polyphenol extraction. Overall, the MWDA extraction process presented here enables the fast, cheap and tunable processing of food waste yielding a high amount of valuable bioactive compounds.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
跳跃的乐萱完成签到 ,获得积分10
刚刚
摇光完成签到,获得积分10
1秒前
SESAME复合体完成签到,获得积分10
4秒前
BINBIN完成签到 ,获得积分10
7秒前
9秒前
ruby完成签到,获得积分10
9秒前
漂亮小鸽子完成签到,获得积分10
10秒前
10秒前
执意完成签到 ,获得积分10
10秒前
zorro完成签到,获得积分10
10秒前
Phoenix ZHANG完成签到 ,获得积分10
10秒前
七七四十九完成签到,获得积分10
11秒前
黑暗精灵完成签到,获得积分10
12秒前
burninhell完成签到,获得积分10
12秒前
wangnn发布了新的文献求助10
13秒前
charles发布了新的文献求助10
14秒前
笨笨千亦完成签到 ,获得积分10
15秒前
李凤凤完成签到 ,获得积分10
18秒前
orixero应助Huimin采纳,获得10
18秒前
小刚完成签到,获得积分0
19秒前
李子完成签到,获得积分10
20秒前
王旭东完成签到 ,获得积分10
20秒前
21秒前
petrichor完成签到 ,获得积分10
21秒前
22秒前
大叉烧完成签到,获得积分10
22秒前
和谐续完成签到 ,获得积分10
23秒前
蓝胖子完成签到,获得积分0
23秒前
小秃兄完成签到,获得积分10
23秒前
明亮剑完成签到 ,获得积分10
24秒前
ShowMaker应助Han采纳,获得30
25秒前
李朝富完成签到,获得积分10
26秒前
高高的元容完成签到,获得积分10
27秒前
吴真心发布了新的文献求助10
28秒前
踏实的盼秋完成签到,获得积分10
29秒前
泠风来完成签到,获得积分10
31秒前
zjuszk完成签到 ,获得积分10
34秒前
boom完成签到 ,获得积分10
34秒前
汉堡包应助lli采纳,获得10
34秒前
清脆初晴完成签到,获得积分10
34秒前
高分求助中
Evolution 10000
Sustainability in Tides Chemistry 2800
The Young builders of New china : the visit of the delegation of the WFDY to the Chinese People's Republic 1000
юрские динозавры восточного забайкалья 800
English Wealden Fossils 700
叶剑英与华南分局档案史料 500
Foreign Policy of the French Second Empire: A Bibliography 500
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3146946
求助须知:如何正确求助?哪些是违规求助? 2798219
关于积分的说明 7827061
捐赠科研通 2454768
什么是DOI,文献DOI怎么找? 1306462
科研通“疑难数据库(出版商)”最低求助积分说明 627788
版权声明 601565