惰性气体
氧气
化学工程
催化作用
碳纤维
异质结
大气(单位)
一氧化碳
光催化
光化学
还原气氛
化学
吸附
材料科学
复合数
复合材料
光电子学
有机化学
工程类
物理
热力学
作者
Hongru Zhou,Min Wang,Feng Wang
出处
期刊:Chem
[Elsevier]
日期:2022-02-01
卷期号:8 (2): 465-479
被引量:75
标识
DOI:10.1016/j.chempr.2021.10.021
摘要
Photocatalytic carbon monoxide (CO) production from biomass is a sustainable route for achieving the carbon-neutral goal, but the current catalytic activity is low. One of the reasons is that the reaction is thermodynamically unfavorable (ΔG >0) in inert atmosphere. The reaction can be transformed into thermodynamically favorable (ΔG <0) in an oxygen-rich atmosphere but it leads to the deep degradation to CO2. Targeting this problem, we herein report an oxygen-controlled photo-reforming process to convert biomass-derived polyols into CO at room temperature. A CdS@g-C3N4 composite shows 48% yield of CO from glycerol in an appropriate O2 atmosphere, which is 13-fold of that in inert atmosphere. The Z-scheme heterojunction and core-shell structure of CdS@g-C3N4 not only efficiently promote charge separation and the enrichment of photogenerated electrons on the g-C3N4 shell but also facilitate the adsorption and activation of dioxygen. This study provides a new oxidative photo-reforming strategy to produce CO from biomass under mild conditions.
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