离子半径
催化作用
镧系元素
无机化学
碱土金属
氧气
化学
极化(电化学)
钙钛矿(结构)
电极
扩散
离子
物理化学
碱金属
热力学
结晶学
有机化学
物理
生物化学
作者
Takeo Hyodo,Masahiko Hayashi,Norio Miura,Noboru Yamazoe
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:1996-11-01
卷期号:143 (11): L266-L267
被引量:118
摘要
A series of perovskite‐type manganites, (Ln = lanthanoids or Y), were examined for their electrode‐catalytic activities to reduce oxygen in alkaline solution. Polarization experiments using gas diffusion‐type electrodes revealed that the catalytic activity differed significantly with a change in Ln, being in the order of . This order coincides with the decreasing order of the ionic radius of .
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