Temporal Spinodal Decomposition of the Fe1+yTe1−xSex Crystals and its Impact on Superconducting Properties

Precipitated phases, formed by spinodal decomposition during long‐term storage in a desiccator in dry atmosphere, are found with the X‐ray diffraction (XRD) study of Fe 1+ y Te 1− x Se x crystals. Their compositions are deduced from the position of satellite Bragg reflections in the XRD pattern. In particular, in the Fe 1.19 Te 0.58 Se 0.42 crystal, traces of phases with significantly higher tellurium content, namely Fe 1+ y Te 0.9 Se 0.1 and FeTe, are found. The detection and analysis of side bands in the diffraction pattern of an aged crystal indicate spinodal decay. It leads to the formation of a modulated structure in the entire volume of the sample and to strain in the crystal structure. In turn, this results in a significant improvement in the superconducting characteristics. Specifically, the resistive transition narrows to 2 K at the onset temperature 14.5 K, and the superconducting volume fraction increases up to about 100%.