Ceramic nanofiber membrane anchoring nanosized Mn2O3 catalytic ozonation of sulfamethoxazole in water

Catalytic ceramic nanofiber membranes (Mn@CNMs) were prepared by anchoring Mn2O3 nanoparticles on the pits of attapulgite (APT) nanofibers via an impregnation and in-situ precipitation method. An integrated catalytic ozonation/membrane filtration process applying Mn@CNM was employed to degrade sulfamethoxazole (SMX) and the removal achieved up to 81.3% during a 7-h continuous filtration. The reactive oxygen species (ROS) quenching and radical detection experiments were conducted to determine the contribution of 1O2, ·OH and O2·- towards the catalytic degradation of SMX. Moreover, Mn@CNM exhibited wide applicability for real water matrix and the total removal of various kinds of emerging contaminants in real hospital wastewater reached up to 98.5%. The excellent performances of Mn@CNM were attributed to the nano-confinement effect in the membrane layer. First, anchoring Mn2O3 nanoparticles on the pits of the APT surface suppressed the growth and aggregation of nanosized Mn2O3, providing abundant reactive sites for catalytic ozonation. Second, the interlaced APT nanofibers formed nano-sized network structures, where ROS and SMX were confined in close vicinity and ROS have more chances to attack SMX. This work provides a promising strategy for the preparation of catalytic ceramic membrane with high catalytic efficiency for degradation of emerging contaminants in water.