Mn-vacancy birnessite for photo-assisted elimination of formaldehyde at ambient condition

Visible light-assisted catalysis has recently attracted considerable attention because it is efficient, cost effective, and does not cause indoor air pollution. Several birnessite-type MnO2 catalysts with different numbers of manganese vacancies (MVs) were synthesized in this study and used for photo-assisted catalytic oxidation of HCHO. Under visible light irradiation, MVs act as trapping centers to accelerate electrons transport and produce abundant reactive radicals to boost the activation of molecular oxygen, thereby improving the catalytic HCHO oxidation. The birnessite with the highest number of MVs exhibits remarkable oxidation activity with 80 ppm of HCHO (42% HCHO conversion was attained at ambient temperature) and a corresponding gas hourly space velocity (GHSV) of 60 L/(g·h) in a dynamic experiment. Moreover, it mineralizes 80 ppm of HCHO within 160 min in a static experiment, whereas it only takes 90 min under the same conditions with the visible light irradiation. The activity factor of birnessite with the highest MV content under visible light irradiation is 2.2 times that observed under dark conditions. Overall, this study elucidates the photothermal catalytic oxidation of HCHO, and concludes that the birnessite comprising MVs is a promising material for air purification applications.