Degradation or humification: rethinking strategies to attenuate organic pollutants

The fate of organic pollutants in environmental matrices can be determined by degradation and humification. The humification process represents a promising strategy to remove organic pollutants, particularly those resistant to degradation. In contrast to the well-studied degradation process, the contribution and application prospects of the humification process for organic pollutant removal has been underestimated. The recent progress in synthesizing artificial humic substances (HS) has made directed humification of recalcitrant organic pollutants possible. This review focuses on degradation and humification of organic matter, especially recalcitrant organic pollutants. Challenges in understanding the contribution, underlying mechanisms, and artificial synthesis of HS for removing organic pollutants are also critically discussed. We advocate further investigating the humification of organic pollutants in future studies.