优等
渗透系数
化学
摩尔浓度
活度系数
非随机双液模型
热力学
三元运算
理想溶液
状态方程
三元数制
混合(物理)
水溶液
物理化学
有机化学
相(物质)
物理
量子力学
计算机科学
程序设计语言
作者
Francisco J. Passamonti,María R. Gennero de Chialvo,Abel C. Chialvo
标识
DOI:10.1016/j.fluid.2022.113464
摘要
A method is proposed for the evaluation of the activity coefficients of a solution constituted by a solvent (1) and two non-volatile molecular solutes (2,3) from the experimental dependence of the osmotic coefficient of the ternary solution (1,2,3) on composition. A generalized analytical expression is derived to describe such dependence, based on the sum of the weighted contributions of both binary systems and the contribution due to the mixing effect. With the resulting expression and using the solution of the Gibbs-Duhem differential equation for ternary systems, the equations that allows the evaluation of the corresponding experimental activity coefficients of both solutes in ideal dilute solution reference state (molality scale) are derived. From the comparative analysis and discussion of the results obtained for three ternary systems, it was possible to verify that the proposed methodology provides a rigorous alternative to evaluate suitable values of activity coefficients from experimental data of osmotic coefficients. Finally, in order to facilitate the correlation of these values with equations originated in molecular solution modelling (NRTL, UNIQUAC, etc.), the relationships between the corresponding reference states and concentration scales were established.
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