Coupled effects of temperature and compressive strain on aging of silicone rubber foam

材料科学 压缩永久变形 微观结构 复合材料 硅橡胶 热重分析 抗压强度 傅里叶变换红外光谱 应力松弛 硅酮 热稳定性 衰减全反射 天然橡胶 化学工程 蠕动 工程类
作者
Weitao Lou,Chaoyang Xie,Xuefei Guan
出处
期刊:Polymer Degradation and Stability [Elsevier BV]
卷期号:195: 109810-109810 被引量:25
标识
DOI:10.1016/j.polymdegradstab.2021.109810
摘要

• The long-term thermal-oxidative aging behaviors and mechanisms of silicone rubber foam at various levels of elevated temperature and compressive strain were studied. • The complex oxidation reactions occurred simultaneously with the formation of oxidation products. • The physical and mechanical properties of the foams underwent significant changes due to the oxidation reactions and the irreversible collapse of the porous microstructure. The coupled effects of temperature and compressive strain on aging behaviors and mechanisms of silicone rubber foam were investigated by conducting the accelerated aging tests. The silicone rubber foams subjected to various levels of temperature and compressive strain were characterized by Attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy, micro hardness, volume fraction, compression set, continuous stress relaxation, mechanical properties, and thermogravimetric analysis (TGA) etc. The ATR-FTIR results indicate that the complex oxidation reactions (crosslinking, chain scission, and oxidation of side chains) occurred simultaneously with the formation of oxidation products. The high temperature facilitated the increase in crosslinking density and enhanced the thermal stability of the foams, implying that the oxidation crosslinking predominated over chain scission leading to the formation of a denser network structure. The physical and mechanical properties of the foams underwent significant changes due to the oxidation reactions and the irreversible collapse of the porous microstructure. The elevated temperature and the compressive stress both have a direct effect on the degradation of the foam. The elevated temperature played a more important role in changes of the physical-mechanical properties and microstructure.
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