Adsorption of Anionic Polyacrylamide onto Coal and Kaolinite Calculated from the Extended DLVO Theory Using the van Oss-Chaudhury-Good Theory

The dispersion behavior of particles is of great significance in selective flocculation flotation. The interfacial interaction between coal and the main impurity mineral (kaolinite) particles with the effect of an anionic polyacrylamide (PAM A401) was explored by the extended Derjagin⁻Landau⁻Verwey⁻Overbeek (DLVO) theory. The involved surface free energy components of fine mineral particles were estimated using the van Oss-Chaudhury-Good theory and Washburn equation. After adsorption of PAM A401, the range and absolute value of the hydrophobic interaction VHA of the coal particles decreased, the electrostatic repulsive potential increased, and the total potential energy changed from -1.66 × 10⁵ to -4.03 × 10⁴ kT at the separation distance of 5 nm. For interactions between the kaolinite and coal particles after PAM A401 adsorption, the electrostatic repulsive potential increased and the hydrophilic repulsive potential energy decreased. The energy barrier at the separation distance of 0.2 nm decreased from 2.78 × 10⁴ to 2.29 × 10⁴ kT. The total potential energy between the kaolinite and coal particles after PAM A401 adsorption was still repulsive, and the range of the repulsive interaction increased from ~0.05 to 47 nm to ~0.05 to 50 nm. The total potential energy of the coal particles after PAM A401 adsorption was still attractive. This behavior of coal and kaolinite particles with the effect of PAM A401 indicates the possibility of enhanced fine coal separation by the method of selective flocculation flotation.