材料科学
阳极
碳化硅
闪光灯(摄影)
纤维
相(物质)
焚化
碳纤维
硅
复合材料
废物管理
冶金
复合数
电极
艺术
物理化学
视觉艺术
有机化学
化学
工程类
作者
Yi Cheng,Jinhang Chen,Bing Deng,Weiyin Chen,Karla Silva,Lucas Eddy,Gang Wu,Ying Chen,Bowen Li,Carter Kittrell,Shichen Xu,T.Z. Si,Ángel A. Martí,Boris I. Yakobson,Yufeng Zhao,James M. Tour
标识
DOI:10.26434/chemrxiv-2023-bb9b0
摘要
The increasing use of fiber-reinforced plastic has triggered an urgent demand for its recycling once it reaches its end-of-life. Currently, landfilling and incineration are major disposal methods of fiber-reinforced plastic, which lead to undesirable waste of resources and environmental contamination. To address this issue, we disclose a solvent-free and energy-efficient flash upcycling method to convert the mixture of glass fiber-reinforced plastic and carbon fiber-reinforced plastic into SiC powders within seconds and in yields of >90%. By modulating input pulse voltages and flash times, SiC with two different phases, 3C-SiC and 6H-SiC, can be selectively synthesized, each with phase purity of 90-99%. Theoretical simulations reveal that the increasing content of Si vacancy during flash process dominates the phase transformation from 3C-SiC to 6H-SiC. The SiC powders are further used as the anode material for lithium-ion batteries, which yields a phase-dependent performance. The 3C-SiC anode exhibits superior reversible capacity (741 mAh·g-1 at 0.2 C) and rate performance over the 6H-SiC anode (626 mAh·g-1 at 0.2 C), while both show excellent cycling stability (~95% capacity retention after 200 cycles). Life cycle assessment reveals the flash upcycling process greatly reduces the energy demand, greenhouse gas emission and water consumption over other recycling processes.
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