蚀刻(微加工)
熔盐
材料科学
各向同性腐蚀
金属
亚稳态
化学工程
无机化学
纳米技术
冶金
化学
有机化学
图层(电子)
工程类
作者
Junji Mou,Shibo Li,Weiwei Zhang,Weimin Xu,Shukai Fan,Guoping Bei
标识
DOI:10.26599/jac.2023.9220729
摘要
Two-dimensional (2D) MoB metal borides (MoB MBene) have attracted much attention due to their fascinating properties and functional applications. So far, work on the synthesis of 2D MoB nanosheets by acid or alkaline etching of MoAlB has not been very successful. It has been proposed that the 2D MoB MBene may be fabricated by chemical etching of a Mo2AlB2 precursor, but further investigations were not performed possibly due to the difficult preparation of the metastable Mo2AlB2 compound at high temperatures by solid-state reactions. Here, we report on the successful synthesis of the Mo2AlB2 compound and 2D MoB nanosheets by the deintercalation of Al from MoAlB through a ZnCl2 molten salt etching approach at relatively low temperatures. The influence of etching temperature, etching time, and starting mixtures on the formation of desirable phases have been investigated. A pure Mo2AlB2 compound was synthesized at temperatures below 600 ℃, while the 2D MoB MBene nanosheets were obtained at 700 ℃ through the molten salt etching of MoAlB. In addition, the present work further confirms that the MoB MBene can be prepared by etching the as-synthesized Mo2AlB2 precursor in LiF–HCl solution. Our work demonstrates that the molten salt etching is an effective method to prepare 2D MoB MBene.
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