MnO2/polypyrrole-electrodeposited carbonized paper fiber-based for flexible asymmetric supercapacitors with high electrochemical and mechanical reliability

超级电容器 材料科学 聚吡咯 电极 碳化 电化学 纤维 可靠性(半导体) 化学工程 纳米技术 复合材料 聚合物 化学 工程类 扫描电子显微镜 物理化学 功率(物理) 物理 量子力学 聚合
作者
Mengying Jia,Ziyu Zhao,Meng Wang,Yucheng Zhou
出处
期刊:Journal of energy storage [Elsevier BV]
卷期号:55: 105288-105288 被引量:12
标识
DOI:10.1016/j.est.2022.105288
摘要

The rapid development of intelligent electronic products and wearable devices has stimulated the research upsurge on flexible supercapacitors. However, achieving supercapacitors with both high flexibility and high energy density remains a huge challenge. Herein, we develop a novel strategy to fabricate flexible asymmetric supercapacitor comprised of carbonized paper fiber/graphene/tannic acid (CGTA), manganese dioxide (MnO 2 ) and polypyrrole (PPy) based film electrode. The electrode synthesized via electrochemical deposition avoided the necessity to use non-conductive binders and offered excellent electrochemical performance. The resultant MnO 2 @CGTA and PPy@CGTA film electrode exhibit high areal specific capacitance of 0.97 F cm −2 and 0.99 F cm −2 at a current density of 1 mA cm −2 , respectively. The structural integrity provided by MnO 2 @CGTA and PPy@CGTA film electrode facilitated excellent electrochemical stability with capacitance retention of 89.93 % and 91.06 % after 5000 charge/discharge cycles, respectively. Furthermore, the flexible asymmetric supercapacitor (MnO 2 @CGTA//PPy@CGTA) is assembled and it demonstrates high specific capacitance of about 1.383 F cm −2 at 1 mA cm −2 , excellent energy density of 192.08 μWh cm −2 at a power density of 0.5 mW cm −2 , and good cycle stability of 90.12 % capacitance retention after 10,000 charge/discharge cycles. Even after 500 bending/unbending cycles, still about 86.43 % of its initial capacitance is retained. • A flexible asymmetric supercapacitor comprised of carbonized paper fiber based film electrode is designed. • The electrode synthesized via electrochemical deposition avoided the necessity to use non-conductive binders. • The FSCs demonstrates high energy density of 192.08 μWh cm -2 at a power density of 0.5 mW cm −2 . • This work provides the possibility for the application for the FSCs on intelligent electronic products and wearable devices.
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