Nickel‐Doped Carbon Dots as an Efficient and Stable Electrocatalyst for Urea Oxidation

Abstract Urea is a typical contaminant present in wastewater which may cause severe environmental problems. Electrochemical catalytic oxidation of urea has emerged as an efficient approach to solve this problem. Nevertheless, the current nickel‐based catalysts (e.g., nickel hydroxide/sulfides) feature a high metal content. It not only lowers the utilization efficiency of nickel but also causes secondary pollution to the environment. Here, nickel‐doped carbon dots (Ni‐CDs) with an excellent and stable catalytic activity for the electrocatalytic urea oxidation reaction (UOR) are reported. Specifically, carbon dots (CDs) with abundant functional groups are synthesized by a one‐pot hydrothermal method and then Ni‐CDs with a very low metal content (1.1 at%) are prepared. The Ni 2+ sites by coordination with carboxylic groups on the CDs provide excellent electrocatalytic activity and excellent durability for the UOR, as demonstrated by an anodic current density of 100 mA cm −2 at a potential of 1.38 V (vs RHE) and similar experimental results in practical application. To the best of knowledge, this is the first report of CDs‐based materials applied for the UOR, which opens an important new area of applicability for CDs as well as broadens the scope of the materials for electrochemical catalysis of urea.