吸附
解吸
多重分形系统
煤
分形维数
化学
赫斯特指数
热力学
矿物学
分形
材料科学
物理化学
数学
物理
统计
有机化学
数学分析
作者
Zhenyang Wang,Gang Wang,Congmeng Hao,Biao Hu,Yuanping Cheng,Zhen Liu,Guansheng Qi
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2023-07-24
卷期号:37 (15): 10915-10928
被引量:3
标识
DOI:10.1021/acs.energyfuels.3c01230
摘要
Although the coal pore structure is attracting the attention of researchers, studies on the multifractal and gas adsorption/desorption capacity are relatively few. In this study, multifractal characteristics were analyzed, and their effects on gas adsorption/desorption were discussed. The results showed that metamorphism and tectonism affected gas adsorption/desorption by changing the coal pore structure. The limit gas adsorption volume and initial desorption rate of tectonic coals increased by 3.9%–23.9% and 1.96–2.7 times, respectively. The information dimension (D1), correlation dimension (D2), and classical Hurst index gradually decreased with metamorphism and tectonism, while the Hausdorff dimension and Δα gradually increased, indicating that pore size distribution (PSD) was more decentralized or inhomogeneous. The evaluation results of the correlation between multifractal parameters and complexity confirmed its accuracy in assessing pore complexity. Multifractal parameters have a significant impact on gas adsorption/desorption capacity overall, mainly by reflecting the concentration degree, local density, and homogeneity of pores.
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