共聚物
质子交换膜燃料电池
联苯
膜
导电体
质子
材料科学
高分子化学
燃料电池
化学工程
功率密度
化学
功率(物理)
聚合物
有机化学
复合材料
热力学
物理
工程类
量子力学
生物化学
作者
Hai Lin,Yichang Ma,Xiaocan Wang,Guiqin Yi,Ai Mei Zhu,Qinglin Liu,Qiu Gen Zhang
标识
DOI:10.1016/j.memsci.2024.122479
摘要
Ether-free proton exchange membranes (PEMs) based on aromatic polymers are considered as potential alternatives to perfluorosulfonic acid (PFSA) PEMs due to their low cost, less reactant crossing, exceptional chemical stability and outstanding thermal stability. Herein, a series of high-performance sulfonated poly(biphenyl alkylene) (BPSA-PT-x) membranes with full carbon chain backbones were synthesized to investigate the effect of different ratios of hydrophobic components on membrane properties. Among the prepared membranes, the BPSA-PT-10 % PEM with the highest proton conductivity (311 mS cm-1 at 80 °C water) possessed excellent dimensional stability (in-plane swelling rate ≤19.7 %, through-plane swelling rate ≤24.9 %), mechanical properties (elongation at break: 89.8 % in wet state), thermal stability (glass transition temperature >450 °C) and low H2 crossover (1.80 mA cm-2). Further, the assembled H2/O2 fuel cell based on BPSA-PT-10 % PEM exhibited competitive performance with a peak power density of 2.62 W cm-2. The developed poly(biphenyl alkylene)-based PEMs should have potential applications in hydrogen energy field.
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