Hemp fiber reinforced dual dynamic network vitrimer biocomposites with direct incorporation of amino silane

材料科学 复合材料 硅烷 热固性聚合物 纤维 天然纤维 聚合物 复合数
作者
Mingen Fei,Wangcheng Liu,Lin Shao,Yiding Cao,Brian J. Bliss,Baoming Zhao,Jinwen Zhang
出处
期刊:Chemical Engineering Journal [Elsevier BV]
卷期号:480: 148091-148091 被引量:17
标识
DOI:10.1016/j.cej.2023.148091
摘要

Natural fiber composites are inexpensive and renewable alternatives to traditional fiber reinforced polymers (FRPs). However, existing natural fiber composites primarily rely on petrochemical based thermosetting matrices, which are difficult to recycle due to their stable crosslinked network structures. To address this challenge, it is desirable to develop natural fiber composites with inherently recyclable biobased matrices. In this study, we developed a dual dynamic network vitrimer matrix from hempseed oil and limonene derivatives and demonstrated its application in hemp fiber reinforced composites. To improve the weak interface between hemp fiber and the polymer matrix, a common challenge in the realm of natural fiber composites, we directly incorporated amino silane into the vitrimer matrix. The amino silane participated in the polymer network, increasing the crosslink density and toughening the matrix, as evidenced by the significant improvement of impact strength from 3.5 kJ/m2 to 10.3 kJ/m2. Moreover, the incorporation of amino silane resulted in a lower water absorption by 11 % in a 7-day soaking for the composites, demonstrating improved fiber/matrix interfacial interaction. Furthermore, our biobased vitrimer matrix exhibits both imine and hydroxy-ester dynamic bonds, which enable the recycling of the biocomposite through a mild and cost-effective aminolysis process (100 °C, 3 h, ambient pressure). The decomposed polymer matrix was successfully reused as a polyol for polyurethane adhesives, and the surface morphology of recovered hemp fibers was analyzed and compared with that of the original fibers. These findings will help broaden the use of vitrimers for practical natural fiber composite applications, raise awareness of the problem of recycling natural fiber composite waste, and shed light on the interfacial challenge of natural fiber reinforced vitrimer composites.
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