材料科学
结构精修
电化学
阴极
兴奋剂
三元运算
硼
镍
离子
分析化学(期刊)
化学工程
锂(药物)
晶体结构
结晶学
冶金
物理化学
电极
光电子学
色谱法
化学
有机化学
医学
内分泌学
计算机科学
程序设计语言
工程类
作者
Jiatai Wang,Yuanyuan Li,Shishi Wei,Shunli Hou,Geng Zhou,Xiaocen Yan,Ruheng Xi,Xiaoyi Hou
标识
DOI:10.1016/j.ceramint.2023.04.177
摘要
The lattice of the cathode material LiNi0.815Co0.15Al0.035O2 cathode (NCA) was doped with B3+ using a high-temperature solid-phase method, considerably improving the electrochemical properties of the NCA. Results of X-ray diffraction analysis and Rietveld refinement show that B3+ can enhance lattice ordering by minimising Li+/Ni2+ mixing. The scaning electron microscopy observations indicated that the B3+ doped changes the particle morphology. The specific discharge capacities of 1.5%B-NCA were 178.31 and 123.74 mAhg−1 at 0.2 and 5C, respectively. After 100 cycles, the specific discharge capacity was 176.29 mAhg−1 at 0.2C with a capacity retention of 98.87%. Boron doping significantly improves the structural stability of nickel-rich cathode materials by suppressing the detrimental H2→H3 phase transition, thus improving the electrochemical performance of nickel-rich ternary lithium-ion batteries.
科研通智能强力驱动
Strongly Powered by AbleSci AI