Building Robust Manganese Hexacyanoferrate Cathode for Long‐Cycle‐Life Sodium‐Ion Batteries

Abstract Manganese Hexacyanoferrate (Mn─HCF) is a preferred cathode material for sodium‐ion batteries used in large‐scale energy storage. However, the inherent vacancies and the presence of H 2 O within the imperfect crystal structure of Mn─HCF lead to material failure and interface failure when used as a cathode. Addressing the challenge of constructing a stable cathode is an urgent scientific problem that needs to be solved to enhance the performance and lifespan of these batteries. In this review, the crystal structure of Mn─HCF is first introduced, explaining the formation mechanism of vacancies and exploring the various ways in which H 2 O molecules can be present within the crystal structure. Then comprehensively summarize the mechanisms of material and interfacial failure in Mn─HCF, highlighting the key factors contributing to these issues. Additionally, eight modification strategies designed to address these failure mechanisms are encapsulated, including vacancy regulation, transition metal substitution, high entropy, the pillar effect, interstitial H 2 O removal, surface coating, surface vacancy repair, and cathode electrolyte interphase reinforcement. This comprehensive review of the current research advances on Mn─HCF aims to provide valuable guidance and direction for addressing the existing challenges in their application within SIBs.