Ionogel Adhesives: From Structural Design to Emerging Applications

Abstract Adhesives are indispensable in both daily household applications and advanced industrial settings, where they must deliver exceptional bonding performance. Ionogel adhesives, which feature a supporting polymer network infused with ionic liquid (IL), have emerged as promising candidates due to their unique structural and functional properties. The presence of ionic species within ionogels promotes non‐covalent interactions—such as ionic bonds, ion‐dipole interactions, and hydrogen bonding—that enhance both cohesion within the material and adhesion to various substrates. These characteristics make ionogels ideal for applications that require robust adhesive performance, especially in demanding environments. Despite the growing interest in ionogel adhesives, a comprehensive review of the latest advancements in this area is lacking. This paper aims to fill this gap by categorizing ionogel adhesives based on their composition and discussing strategies to enhance their adhesive properties. Additionally, novel ionogel adhesives designed for specific applications are highlighted. Finally, the current state of research is summarized, and offers insights into the challenges and future opportunities for the development of ionogel adhesives.