加氢脱硫
催化作用
浸出(土壤学)
惰性
化学
催化剂载体
化学工程
金属
无定形固体
无机化学
多相催化
材料科学
有机化学
工程类
环境科学
土壤科学
土壤水分
作者
Shalini Arora,Sri Sivakumar
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2023-05-31
卷期号:37 (12): 8539-8551
被引量:2
标识
DOI:10.1021/acs.energyfuels.3c00893
摘要
The formation of NixSy/CoxSy phases on the HDS catalyst surface during catalyst preparation poses the following challenges in the HDS reaction: (1) inactive in the reaction, (2) hinder the role of promoters, (3) block the actives sites (NiMoS/CoMoS) at the perimeter, and (4) increase the inert mass on the catalyst surface. Since the formation of NixSy/CoxSy phases is thermodynamically favorable, it is difficult to control this during the catalyst synthesis. In this regard, this work investigates the effect of metal-support interactions and catalyst compositions on NixSy phase separation and removal of NixSy phases from the catalyst surface using acid-leaching method. The HDS activity for NiMo supported on amorphous alumina (NiMo/A-Al2O3) catalysts significantly increased after the acid-leaching treatment by unblocking the active NiMoS sites and increasing the Ni-MoS2 interaction through alumina support leaching. Overall, the HDS activity for leached NiMo/A-Al2O3 catalysts is 25–30% higher than that for conventional NiMo/γ-Al2O3 catalysts.
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