超级电容器
杂质
共轭体系
退火(玻璃)
材料科学
碳纤维
实现(概率)
化学工程
纳米技术
电极
复合数
化学
有机化学
电化学
物理化学
聚合物
复合材料
工程类
统计
数学
作者
Xiaohui Yan,Qihui Guo,Wenxia Huang,Yige Xiong,Siqi Jing,Xin Zhang,Fengyu Huang,Xiang Ge
摘要
Abstract The realization of carbon neutralization requires further development of high‐performance supercapacitors, while their wider applications are limited by serious self‐discharge. This work proposes a conjugately configured supercapacitor, as well as the strategy for optimizing the structure of active materials specifically for such supercapacitor. The conjugated supercapacitor consists of pairs of prelithiated T‐Nb 2 O 5 @C and forms a Li x Nb 2 O 5 @C versus Li 2 − x Nb 2 O 5 @C configuration. We demonstrate that the elegant control of the coated carbon shell has a significant effect on the self‐discharge behavior. An optimized annealing temperature of 300°C is beneficial for reducing the elemental impurity while not introducing microregional phase impurity, thus leading the best resistance towards self‐discharge. When the conjugated supercapacitor is charged to an initial voltage of 1.0 V, the voltage could retain for more than 3000 min before dropping to 0.5 V. This work is expected to provide general guidance for optimizing the active materials for conjugated supercapacitors.
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