吸收(声学)
电磁辐射
材料科学
陶瓷
反射损耗
阻抗匹配
相(物质)
三元运算
电阻抗
光电子学
光学
物理
复合材料
计算机科学
复合数
量子力学
程序设计语言
作者
Youbing Li,Huigang Wei,Lu Chen,Chaoyin Xie,Haoming Ding,Fei Fang,Zhifang Chai,Qing Huang
出处
期刊:ACS Nano
[American Chemical Society]
日期:2024-03-28
卷期号:18 (14): 10019-10030
被引量:1
标识
DOI:10.1021/acsnano.3c11585
摘要
MAX phases are highly promising materials for electromagnetic (EM) wave absorption because of their specific combination of metal and ceramic properties, making them particularly suitable for harsh environments. However, their higher matching thickness and impedance mismatching can limit their ability to attenuate EM waves. To address this issue, researchers have focused on regulating the electronic structure of MAX phases through structural engineering. In this study, we successfully synthesized a ternary MAX phase known as Sc2GaC MAX with the rare earth element Sc incorporated into the M-site sublayer, resulting in exceptional conductivity and impressive stability at high temperatures. The Sc2GaC demonstrates a strong reflection loss (RL) of −47.7 dB (1.3 mm) and an effective absorption bandwidth (EAB) of 5.28 GHz. It also achieves effective absorption of EM wave energy across a wide frequency range, encompassing the X and Ku bands. This exceptional performance is observed within a thickness range of 1.3 to 2.1 mm, making it significantly superior to other Ga-MAX phases. Furthermore, Sc2GaC exhibited excellent absorption performance even at elevated temperatures. After undergoing oxidation at 800 °C, it achieves a minimum RL of −28.3 dB. Conversely, when treated at 1400 °C under an argon atmosphere, Sc2GaC demonstrates even higher performance, with a minimum RL of −46.1 dB. This study highlights the potential of structural engineering to modify the EM wave absorption performance of the MAX phase by controlling its intrinsic electronic structure.
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