阻燃剂
气凝胶
深共晶溶剂
木质纤维素生物量
材料科学
生物量(生态学)
产量(工程)
原材料
化学工程
共晶体系
热稳定性
溶剂
环境友好型
试剂
制浆造纸工业
复合材料
有机化学
化学
木质素
微观结构
生态学
海洋学
工程类
地质学
生物
作者
Yeling Zhu,Zhengyang Yu,Jiaying Zhu,Yifan Zhang,Xueyong Ren,Feng Jiang
标识
DOI:10.1016/j.cej.2022.136748
摘要
The global consensus to pivot to a more sustainable lifestyle and achieve greater atom economy calls for not only sourcing advanced functional materials from biomass but also accomplishing high feedstock utilization with green and low-toxic reagents; yet, the multi-constituent nature of biomass with complex hierarchical structure makes this target difficult to meet. This study focused on the high-yield conversion of low-cost, coarsely pretreated biomass via reactive deep eutectic solvent (DES) pretreatment into lignocellulosic nanofibrils (LCNF) with high aspect ratio (up to ∼ 103) and high sulfate ammonium functionalization (up to 3.53 mmol/g). The aqueous suspension of LCNF exhibited high viscosity and superb colloidal stability. Such LCNF can be directly processed into highly porous aerogel with low apparent density, good mechanical properties, satisfactory thermal insulating performance (κ ranged 31.0–31.6 mW/m∙K) that is comparable to commercial petrochemical-based insulators. Moreover, the surface sulfate ammonium functionalized during DES pretreatment endowed LCNF with intrinsic flame retardancy and self-extinguishing property. Taken together, a facile valorization strategy is developed to convert low-cost renewable resources into functionalized nanofibrils at a high yield, which serve as an intrinsically flame-retardant platform material for thermal insulation applications.
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