阳极
材料科学
碳纤维
电容
化学工程
兴奋剂
钠
离子
纳米技术
化学
电极
光电子学
冶金
复合材料
复合数
有机化学
物理化学
工程类
作者
Yan Zhao,Yao Cong,Hui Ning,Xiang Fei,Chenghao Wu,Heng Wang,Zhengqiu He,Yani Wang,Qingshan Zhao,Mingbo Wu
标识
DOI:10.1016/j.jallcom.2022.165691
摘要
Carbonaceous materials have been regarded as promising materials for sodium-ion batteries (SIBs), owing to their high electrical conductivity and stable chemical properties. High-performance sodium-ion batteries need high quality carbon materials as anodes with low cost. Herein, we report a facile method of preparing N/P co-doped soft carbon nanoboxes (NPSC) using petroleum pitch as raw material. Benefitting from the nanobox-like morphology, expanded graphitic layer spacing and excellent electrical conductivity, the NPSC anodes show fast sodium-ion diffusion and high pseudo capacitance ratio, as a result, excellent rate capability and cycling performance can be achieved. The NPSC can deliver a high reversible capacity of 162 mAh g−1 over 3000 cycles at high current density of 1 A g−1. DFT calculations reveal that N, P co-doping carbon has more electrons near fermi level, thus facilitating electron transport. This work puts forward a convenient method to prepare carbon based anode for high performance SIBs with low cost petroleum pitch.
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