甲醇
正交晶系
催化作用
钌
化学
电解质
粒径
多元醇
无机化学
纳米颗粒
核化学
晶体结构
材料科学
纳米技术
结晶学
有机化学
物理化学
电极
聚氨酯
作者
Qing Gong,Jiwu Zheng,Ye Wang,Shuiping Gong,Weifeng Yang,Xuan Cheng
出处
期刊:Meeting abstracts
日期:2017-09-01
卷期号:MA2017-02 (36): 1611-1611
标识
DOI:10.1149/ma2017-02/36/1611
摘要
The carbon supported ruthenium tellurium (RuTe 2 /C) nanoparticles were synthesized through a simple microwave polyol method and heat treatment at 350℃. Effects of Ru/Te molar ratio on the crystal structure, surface morphology, microstructure, electrocatalytic activity and stability, as well as methanol tolerance in both acidic and alkaline solutions were systematically investigated. The orthorhombic RuTe 2 and hexagonal Ru were formed. The catalyst nanoparticles were uniformly dispersed on carbon support and the average particle size ranged 5.0~8.6 nm. The best activities toward oxygen reduction reaction (ORR) were achieved with the RuTe 2 /C catalyst prepared at Ru/Te=1:1 in both acidic and alkaline media. The onset ( E onset ) and half-wave potentials ( E 1/2 ) were 0.88 and 0.60 V in 0.1 mol/L HClO 4 , respectively, while 0.98 and 0.72 V in 0.1 mol/L KOH, respectively. The E 1/2 values decreased by 5 mV after 1000 cycles in both acidic and alkaline electrolytes, while 20 mV and 7 mV in both acidic and alkaline electrolytes containing 2 mol/L methanol, respectively, suggesting the excellent stability and methanol tolerance.
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