中间相
中胚层
液晶
材料科学
异恶唑
芳基
溶解度
结晶学
分子
分子动力学
侧链
高分子化学
有机化学
计算化学
液晶
复合材料
聚合物
化学
烷基
光电子学
作者
Aloir A. Merlo,Itamar Luís Gonçalves,Vladimir Lavayen,Paolo Roberto Livotto,Cristiane Seganfredo Weber,Renato Arthur Paim Halfen,David M. Walba,Rafaela da Rosa
标识
DOI:10.1080/02678292.2021.2005164
摘要
Bis-1,3-isophthalimines flanked by two side 3-aryl-5-perfluoroalkylisoxazoline or 3-aryl-5-perfluoroalkylisoxazol arms were produced and liquid crystal properties were analysed. Monotropic smectic A mesophase was found for bis-1,3-isophthalimines containing the 3-aryl-5-perfluorooctylisoxazoline (8b). Thermal behaviour was analysed and discussed by DSC, POM, DFT calculations, cohesive energy density (CED), Hildebrand solubility parameters and molecular-shape features. Notably, for long side arm perfluorooctyl 8b, the reduced value of CED is partially compensated by molecular shape of the molecules in the condensed state favouring the SmA mesophase formation.
科研通智能强力驱动
Strongly Powered by AbleSci AI