Layered Double Hydroxide Surface Modified with (3‐aminopropyl)triethoxysilane by Covalent Bonding

三乙氧基硅烷 共价键 材料科学 氢氧化物 分子 表面改性 胺气处理 高分子化学 催化作用 层状双氢氧化物 无机化学 有机化学 化学工程 化学 复合材料 工程类
作者
Ah‐Young Park,Hyuk‐Jun Kwon,Ae Ja Woo,S.‐J. Kim
出处
期刊:Advanced Materials [Wiley]
卷期号:17 (1): 106-109 被引量:97
标识
DOI:10.1002/adma.200400135
摘要

Advanced MaterialsVolume 17, Issue 1 p. 106-109 Communication Layered Double Hydroxide Surface Modified with (3-aminopropyl)triethoxysilane by Covalent Bonding† A.-Y. Park, A.-Y. Park Division of Nano Sciences and Department of Chemistry, Ewha Womans University 11-1 Daehyun-dong , Seodaemun-gu, Seoul 120-750, South KoreaSearch for more papers by this authorH. Kwon, H. Kwon Division of Nano Sciences and Department of Chemistry, Ewha Womans University 11-1 Daehyun-dong , Seodaemun-gu, Seoul 120-750, South KoreaSearch for more papers by this authorA. J. Woo, A. J. Woo Department of Science Education, Ewha Womans University, 11-1 Daehyun-dong, Seodaemun-gu, Seoul 120-750, South KoreaSearch for more papers by this authorS.-J. Kim, S.-J. Kim [email protected] Search for more papers by this author A.-Y. Park, A.-Y. Park Division of Nano Sciences and Department of Chemistry, Ewha Womans University 11-1 Daehyun-dong , Seodaemun-gu, Seoul 120-750, South KoreaSearch for more papers by this authorH. Kwon, H. Kwon Division of Nano Sciences and Department of Chemistry, Ewha Womans University 11-1 Daehyun-dong , Seodaemun-gu, Seoul 120-750, South KoreaSearch for more papers by this authorA. J. Woo, A. J. Woo Department of Science Education, Ewha Womans University, 11-1 Daehyun-dong, Seodaemun-gu, Seoul 120-750, South KoreaSearch for more papers by this authorS.-J. Kim, S.-J. Kim [email protected] Search for more papers by this author First published: 13 January 2005 https://doi.org/10.1002/adma.200400135Citations: 94 † This work is supported by the Korean Science & Engineering Foundation (ABRL R14-2003-014-01000-0). AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Interlayer surfaces of layered double hydroxide (LDH) have been functionalized with amine moieties by condensation between the hydroxyl groups and (3-aminopropyl)triethoxysilane (APS) molecules via the covalent oxane bonds M-O-Si (M=Zn and Cr) (see Figure). Since the galleries of the modified LDHs have a hydrophobic field, various functional molecules such as enzymes, catalysts, and organic molecules can be incorporated between the LDH layers. REFERENCES 1a B. M. Choudary, M. L. Kantam, V. Neeraja, K. K. Rao, F. Figueras, L. Delotte, Green Chem. 2001, 3, 257. 1b J. C. A. A. Roelofs, D. J. Lensveld, A. J. van Dillen, K. P. de Jong, J. Catal. 2001, 203, 184. 1c J. Santhanalakshmi, T. Raja, Appl. Catal. A 1996, 147, 69. 2a B. M. Choudary, S. Madhi, N. S. Chowdari, M. L. Kantam, B. Sreedhar, J. Am. Chem. Soc. 2002, 124, 14 127. 2b E. Gardner, T. J. Pinnavaia, Appl. Catal. 1998, 167, 65. 2c B. M. Choudary, N. S. Chowdari, K. Jyothi, M. L. Kantam, J. Am. Chem. Soc. 2002, 124, 5341. 2d Z. W. Tong, T. Shichi, K. Takagi, Mater. Lett. 2003, 57, 2258. 2e M. Halma, F. Wypych, S. M. Drechsel, S. Nakagaki, J. Porphyrins Phthalocyanines 2002, 6, 502. 2f R. Dula, K. Wcislo, J. Stoch, B. Grzybowska, E. M. Serwicka, F. Kooli, K. Bahranowski, A. Gawel, Appl. Catal. A 2002, 230, 281. 3a Y. W. You, H. T. Zhao, G. F. Vance, Appl. Clay Sci. 2002, 21, 217. 3b P. C. Pavan, G. de A. Gomes, J. B. Valim, Microporous Mesoporous Mater. 1998, 21, 659. 4 N. Kozai, T. 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Descalzo, D. Jimenez, M. D. Marcos, R. Martínez-Máñez, J. Soto, J. El Haskouri, C. Guillém, D. Beltrán, P. Amorós, M. V. Borrachero, Adv. Mater. 2002, 14, 966. 15 A. Corma, M. S. Galletero, H. Garcia, E. Palomares, F. Rey, Chem. Commun. 2002, 1100. 16 E. L. Crepaldi, P. C. Pavan, J. B. Valim, Chem. Commun. 1999, 155. 17 E. P. Plueddemann, Silane Coupling Agents, 2nd ed., Plenum Press, New York 1990, Ch. 4, 5. 18 E. Crepaldi, P. Pavan, J. Valim, J. Mater. Chem. 2000, 10, 1337. 19 A. Beres, I. Palinko, I. Kiricsi, F. Mizukami, Solid State Ionics 2001, 141–142, 259. 20 S. Sundell, Acta Chem. Scand. A 1971, 31, 799. 21 E. L. Crepaldi, P. C. Pavan, J. Tronto, J. B. Valim, J. Colloid Interface Sci. 2002, 248, 429. 22 T. Ogasawara, A. Nara, H. Okabayashi, E. Nishio, C. J. O'Connor, Colloid Polym. Sci. 2000, 278, 1070. 23 A. Pines, M. G. Gibby, J. S. Waugh, J. Chem. Phys. 1973, 59, 569. Citing Literature Volume17, Issue1January, 2005Pages 106-109 ReferencesRelatedInformation
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