超级电容器
循环伏安法
介电谱
X射线光电子能谱
材料科学
电容
扫描电子显微镜
拉曼光谱
活性炭
分析化学(期刊)
碳纤维
吸附
化学工程
电化学
电极
化学
复合材料
有机化学
物理化学
复合数
工程类
物理
光学
作者
Raghu Raman Rajagopal,L.S. Aravinda,Ravindra Rajarao,Badekai Ramachandra Bhat,Veena Sahajwalla
标识
DOI:10.1016/j.electacta.2016.06.077
摘要
Activated carbons (ACs) have been synthesized by using waste PCBs via physical activation subsequent to pyrolysis processes. The physical and chemical properties of the produced activated carbons were studied using nitrogen adsorption, FT-IR spectroscopy, RAMAN spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy techniques. Among the synthesized ACs, AC with the highest surface area of 700 m2 g−1 produced at 850 °C for a time interval of 5 h was subjected to electrochemical studies. Capacitance behaviour of the obtained AC sample has been evaluated using cyclic voltammetry (CV), galvanostatic charge–discharge (GC-D) measurements and electrochemical impedance spectroscopy (EIS) technique. Specific capacitance (Cspec) values vary from 220, 185 and 156 F g−1 for corresponding scan rate of 30, 50 and 100 mV s−1 respectively. The well-developed surface area properties and good capacitance values associated with nitrogen functionalities indicates the AC developed is a good and suitable candidate for the supercapacitor fabrication.
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