四克隆
辛可宁
化学
选择氟
对映选择合成
辛可宁
芳基
亲电氟化
电泳剂
有机化学
催化作用
烷基
作者
Luana G. de Souza,Jorge L. O. Domingos,Talita de A. Fernandes,Magdalena N. Rennó,José M. Sansano,Carmén Nájera,Paulo R. R. Costa
标识
DOI：10.1016/j.jfluchem.2018.11.007
摘要
The enantioselective electrophilic fluorination of α-aryl-tetralones is promoted by cinchonine/selectfluor combinations. This strategy allows a facile synthesis of the corresponding 2-fluoro-2-aryl-1-tetralones with excellent yields (up to >98%) and moderate to good enantioselectivity (up to74%).
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