化学
对映选择合成
芳基
钌
催化作用
有机化学
组合化学
烷基
作者
Masaaki Yohda,Yasunori Yamamoto
摘要
Ruthenium/Me-BIPAM-catalyzed asymmetric addition of arylboronic acids to methyl 2-formylbenzoates afforded chiral 3-aryl-isobenzofuranones. [RuCl2(p-cymene)]2/Me-BIPAM and RuCl2(PPh3)3/Me-BIPAM catalyst systems tolerate a variety of functional groups and give high yields with high enantioselectivities.
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