锌
阳极
成核
材料科学
电镀(地质)
金属
剥离(纤维)
电偶阳极
图层(电子)
无机化学
化学工程
基质(水族馆)
冶金
化学
电极
纳米技术
复合材料
阴极保护
有机化学
物理化学
工程类
地质学
海洋学
地球物理学
作者
Yongfeng Huang,Ziwen Chang,Wenbao Liu,Wenting Huang,Liubing Dong,Feiyu Kang,Chengjun Xu
标识
DOI:10.1016/j.cej.2021.133902
摘要
Aqueous rechargeable zinc-ion batteries have attracted much attention due to high safety, fast charge/discharge rate, low cost and direct utilization of zinc metal anodes. However, zinc anodes suffer from fundamental issues and elusiveness of critical information such as its nucleation and plating/stripping behaviors. Herein, we explore nucleation pattern of zinc on various metal substrates (Cu, Ag, Ti or Sn) and discover a substrate-dependent plating/stripping behavior. With use of binary diagrams (Ag|Cu, Ti|Cu and Cu|Sn), we found that zinc has a selective deposition on Cu substrates with no nucleation barriers. Theoretical calculation also indicates a relatively low bonding energy between Zn and Cu. Besides, it is also found that Sn inhibits growth of by-product of basic zinc sulfates. Thereafter, we report a layer-by-layer construction of zinc metal (Sn/Cu/Zn) anode for long-life zinc-ion batteries. Our work paves a way to understand plating/stripping behavior of metal anodes and to design layer-by-layer metal anodes for metal batteries.
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