过电位
分解水
材料科学
硒化物
析氧
催化作用
双金属片
钴
纳米孔
化学工程
法拉第效率
阳极
纳米技术
电化学
无机化学
电极
化学
物理化学
有机化学
冶金
光催化
工程类
硒
作者
Sampath Prabhakaran,Jayaraman Balamurugan,Nam Hoon Kim,Joong Hee Lee
出处
期刊:Small
[Wiley]
日期:2020-04-20
卷期号:16 (19)
被引量:56
标识
DOI:10.1002/smll.202000797
摘要
Abstract The development of hierarchical nanostructures with highly active and durable multifunctional catalysts has a new significance in the context of new energy technologies of water splitting and metal–air batteries. Herein, a strategy is demonstrated to construct a 3D hierarchical oxygenated cobalt molybdenum selenide (O‐Co 1− x Mo x Se 2 ) series with attractive nanoarchitectures, which are fabricated by a simple and cost‐effective hydrothermal process followed by an exclusive ion‐exchange process. Owing to its highly electroactive sites with numerous nanoporous networks and plentiful oxygen vacancies, the optimal O‐Co 0.5 Mo 0.5 Se 2 could catalyze the hydrogen evolution reaction and oxygen evolution reaction effectively with a low overpotential of ≈102 and 189 mV, at a current density of 10 mA cm −2 , respectively, and exceptional durability. Most importantly, the O‐Co 0.5 Mo 0.5 Se 2 ||O‐Co 0.5 Mo 0.5 Se 2 water splitting device only entails a voltage of ≈1.53 V at a current density of 10 mA cm −2 , which is much better than benchmark Pt/C||RuO 2 (≈1.56 V). Furthermore, O‐Co 0.5 Mo 0.5 Se 2 air cathode‐based zinc–air batteries exhibit an excellent power density of 120.28 mW cm −2 and exceptional cycling stability for 60 h, superior to those of state‐of‐art Pt/C+RuO 2 pair‐based zinc–air batteries. The present study provides a strategy to design hierarchical 3D oxygenated bimetallic selenide‐based multifunctional catalysts for energy conversion and storage systems.
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