Direct Copper‐Catalyzed C‐H Monofluoroalkylation of Benzoxazoles with 1‐Fluoro‐1‐haloalkanes

The first example of direct C–H bond monofluoroalkylation with 1‐fluoro‐1‐haloalkanes with no adjacent functional groups and with β‐hydrogens has been developed. This transformation offers a straightforward route for the synthesis of a series of monofluoroalkylated benzoxazoles.