亲核细胞
分子间力
烯烃
化学
催化作用
芳基
产量(工程)
基质(水族馆)
组合化学
药物化学
有机化学
分子
材料科学
烷基
冶金
地质学
海洋学
作者
Shuyao Zhang,Chenhuan Wang,Xiaohan Ye,Xiaodong Shi
标识
DOI:10.1002/anie.202009636
摘要
The gold-catalyzed intermolecular oxyarylation of alkenes is reported. This work employed the oxidative addition of aryl iodides to Me-DalphosAu+ for the formation of a AuIII -Ar intermediate. The better binding ability of alkenes over O nucleophiles ensured the success of intermolecular oxyarylation, giving desired products with a broad substrate scope and high efficiency (>50 examples with up to 95 % yield). One-pot converting of methoxy groups into other nucleophiles allowed achieving alkene difunctionalization with the construction of C-N, C-S, and C-C bonds under mild conditions.
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