Coupled phase diagram and thermodynamic analysis of the 18 binary systems formed among Li2Co3, K2Co3,Na2Co3, Lioh, Koh, Naoh, Li2So4, K2So4 and Na2So4

Available phase diagram and thermodynamic data on the eighteen binary systems containing Li+ , Na+, K+, S04=, CO3=, and OH− have been collected and critically assessed. A set of self-consistent thermodynamic parameters describing the free energies of the compounds, solid solutions, and liquid solutions in the binary systems has been formulated. The phase diagrams have been calculated, and estimated error limits of all diagrams are given.