A novel porphyrin-based conjugated microporous nanomaterial for solid-phase microextraction of phthalate esters residues in children's food

A novel porphyrin-based conjugated microporous polymer (PCMP) with microporous structure and nitrogen-rich pyrrole building blocks was synthesized. The PCMP was used as a coating material to prepare solid-phase microextraction (SPME) fibers by sol-gel technique. Due to the toxicity of the phthalate esters (PAEs) and the necessity for their sensitive determinations in some food samples, the SPME fiber was investigated for the extraction of eleven PAEs from six different children's milk beverages prior to their detection by gas chromatography-mass spectrometry. Under the optimal conditions, the linear response range for the PAEs was in the range from 0.03 to 200 µg L-1 and the limits of detection (S/N = 3) for the analytes were 0.01-3.00 μg L-1. The method recoveries for the PAEs were between 80% and 120%, with the relative standard deviations varying from 1.3% to 9.8%. The method was successfully applied for the determination of PAEs in children's milk beverages.