Tartaric acid additive to enhance perovskite multiple preferential orientations for high-performance solar cells

酒石酸 材料科学 钙钛矿(结构) 能量转换效率 化学工程 钝化 相对湿度 纳米技术 光电子学 化学 图层(电子) 有机化学 工程类 柠檬酸 物理 热力学
作者
Zhen Wang,Shuai You,Guanhaojie Zheng,Zengguang Tang,Liujiang Zhang,Junhan Zhang,Xiong Li,Xingyu Gao
出处
期刊:Journal of Energy Chemistry [Elsevier BV]
卷期号:69: 406-413 被引量:11
标识
DOI:10.1016/j.jechem.2022.02.007
摘要

Perovskite film quality is a decisive factor governing the performance and long-term stability of perovskite solar cells (PSCs). To passivate defects for high-quality perovskite films, various additives have been explored in perovskite precursor with notable achievements in the development of high-performance PSCs. Herein, tartaric acid (TA) was applied as additive in perovskite precursor solution to modulate the crystal growth leading to high quality thin films with enhanced multiple preferential orientations favoring efficient charge transport along multiple directions. It is also noticed that TA can improve the energy level alignment in PSCs, which effectively accelerates both carrier extraction and transportation with non-radiative recombination suppressed at the perovskite interfaces. Based on the present perovskite films, the fabricated PSCs achieved an excellent champion power conversion efficiency (PCE) of 21.82% from that of 19.70% for the control device without TA additive. In addition, a PSC with TA additive was shown to exhibit impressive operational stability by retaining 92% of its initial PCE after ∼1200 h of aging at room temperature in ambient air with a relative humidity of about 10%–25%. In summary, the present work demonstrates a facile and versatile approach by using TA as additive in perovskite precursor to fabricate high quality perovskite films with enhanced multiple preferential orientations for high-efficiency stable PSCs.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
bzg发布了新的文献求助10
1秒前
Lucas应助科研通管家采纳,获得30
2秒前
桐桐应助科研通管家采纳,获得10
2秒前
今后应助科研通管家采纳,获得10
2秒前
桐桐应助科研通管家采纳,获得10
2秒前
小马甲应助科研通管家采纳,获得10
2秒前
爆米花应助科研通管家采纳,获得10
2秒前
深情安青应助科研通管家采纳,获得10
2秒前
2秒前
NexusExplorer应助科研通管家采纳,获得10
2秒前
如梦如画完成签到 ,获得积分10
2秒前
华仔应助科研通管家采纳,获得10
2秒前
accepted应助科研通管家采纳,获得10
3秒前
accepted应助科研通管家采纳,获得10
3秒前
3秒前
3秒前
wanci应助科研通管家采纳,获得10
3秒前
3秒前
3秒前
3秒前
ylw发布了新的文献求助10
3秒前
5High_0完成签到 ,获得积分10
4秒前
上官若男应助Zzz采纳,获得10
4秒前
bzg完成签到,获得积分20
7秒前
甜蜜的楷瑞应助王手采纳,获得10
8秒前
糖发人发布了新的文献求助10
8秒前
090完成签到,获得积分10
8秒前
chen发布了新的文献求助10
8秒前
Clyde完成签到,获得积分10
10秒前
10秒前
和谐续完成签到 ,获得积分10
11秒前
大个应助李皓婷采纳,获得10
11秒前
13秒前
chen完成签到,获得积分10
13秒前
Hello应助ylw采纳,获得10
13秒前
14秒前
ChemistryZyh发布了新的文献求助10
14秒前
wensir发布了新的文献求助10
14秒前
端庄千琴完成签到,获得积分10
14秒前
heavennew完成签到,获得积分10
15秒前
高分求助中
【提示信息,请勿应助】关于scihub 10000
Les Mantodea de Guyane: Insecta, Polyneoptera [The Mantids of French Guiana] 3000
徐淮辽南地区新元古代叠层石及生物地层 3000
The Mother of All Tableaux: Order, Equivalence, and Geometry in the Large-scale Structure of Optimality Theory 3000
Global Eyelash Assessment scale (GEA) 1000
Picture Books with Same-sex Parented Families: Unintentional Censorship 550
Research on Disturbance Rejection Control Algorithm for Aerial Operation Robots 500
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 4038569
求助须知:如何正确求助?哪些是违规求助? 3576279
关于积分的说明 11374944
捐赠科研通 3305979
什么是DOI,文献DOI怎么找? 1819354
邀请新用户注册赠送积分活动 892698
科研通“疑难数据库(出版商)”最低求助积分说明 815048