淀粉
己二酸
生物降解
材料科学
结晶度
化学工程
热塑性塑料
挤压
复合材料
高分子化学
有机化学
化学
工程类
作者
Phanwipa Wongphan,Theeraphorn Panrong,Nathdanai Harnkarnsujarit
标识
DOI:10.1016/j.fpsl.2022.100844
摘要
Modified starch enhanced the compatibility and modified the properties of thermoplastic starch (TPS) and polybutylene adipate terephthalate (PBAT) biodegradable films. Native (NS), acetylated (AS), octenyl-succinated (OS) and hydroxypropylated (HS) starch were compounded with PBAT via extrusion. PBAT/TPS (40/60 and 50/50 ratios) blend films were produced by blown-film extrusion and characterized for morphology, crystallinity, thermomechanical properties, mechanical and barrier properties. Topographic and scanning electron micrographs showed diverse dispersion and morphologies of starch granules depending on hydrophobicity that governed interface exposure between incompatible polymers. Hydrophilic starch formed phase separated fibrous-like networks entangled in PBAT at higher TPS ratios. Hydrophobic OS starch improved compatibility and interaction with PBAT, greatly modifying mechanical and barrier properties (82–89%). TPS slightly increased α-relaxation temperature and modified arrangements of aromatic structures in PBAT, involving C-H and C-O bonding, subsequently influencing crystallinity of PBAT and the starch phase. Biodegradation of the blend films was dependent on hydrophilicity of starch, giving the fastest degradation in NS and HS. Findings indicated that hydrophobically modified starch improved compatibility with PBAT for biodegradable packaging, while film properties were highly dependent on the morphology of blend matrices.
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