Mechanical, flowing and microstructural properties of cemented sulfur tailings backfill: Effects of fiber lengths and dosage

尾矿 材料科学 硫黄 极限抗拉强度 泥浆 复合材料 水泥 抗压强度 聚丙烯 烟气脱硫 纤维 冶金 废物管理 工程类
作者
Shenghua Yin,Yongqiang Hou,Xin Chen,Minzhe Zhang
出处
期刊:Construction and Building Materials [Elsevier BV]
卷期号:309: 125058-125058 被引量:39
标识
DOI:10.1016/j.conbuildmat.2021.125058
摘要

• The relationship between flowing properties and sulfur content of cemented sulfur tailings backfill (CSTB) is revealed. • Based on SEM and XRD techniques, the effect of sulfur content variation on mechanical properties of cemented sulfur tailings backfill is investigated. • By adding polypropylene fibers to the CSTB, the prediction models for compressive and tensile strength are proposed considering fiber modification coefficient. • Based on SEM and XRD techniques, the effect of polypropylene fibers on mechanical properties of cemented sulfur tailings backfill is investigated. In this paper, the mechanics, flowing and microstructural properties of the cemented sulfur tailings backfill (CSTB) have been studied by means of flow performance test, uniaxial compression test, scanning electron microscope test and X-ray energy spectrum test. On the basis of previous results, a new way was proposed to improve the mechanical performance of CSTB. The research results show that the fluidity of sulfur tailings slurry increases exponentially with the increase of sulfur content, because the density of sulfide concentrate is greater than that of tailings. The adding of polypropylene fiber will reduce the fluidity of sulfur tailings slurry and the fluidity of the slurry decreases exponentially with the increase of fiber content. The compressive strength and 28d splitting tensile strength of the CSTB both increased first and then decreased with the increase of the sulfur content, and reached the maximum when the sulfur content was 12%. However, the CSTB exhibits obvious strength deterioration characteristics when the curing age exceeds 28 days. The compressive strength and 28d tensile strength of the CSTB both increased first and then decreased with the increase of fiber content, and then, reached the maximum when the fiber content is 0.6%. In addition, the effect of adding polypropylene fiber on improving the tensile strength is better than that of compressive strength. SEM and X-ray energy spectrum analysis results show that a certain amount of secondary gypsum and ettringite crystals can effectively fill the pores in the CSTB, which contributes to the development of strength. However, when the sulfur content exceeds the critical content, there are obvious pore structures and a large number of expansive minerals such as gypsum and ettringite in the CSTB, which leads to the strength deterioration of the CSTB. The special spatial skeleton structure formed by polypropylene fibers in the CSTB matrix can play a significant physical reinforcement effect and the reinforcement effect is mainly controlled by the bonding effect between the fiber and the CSTB matrix interface. In addition, the compressive strength, tensile strength and fluidity prediction models of the fiber reinforced CTSB constructed based on the fiber modification coefficient can accurately predict the compressive strength, tensile strength and fluidity parameters, which can provide certain guidance for engineering applications.
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